Spokes can be used to improve wheel alignment, but if the wheel does bend, any work done with the spokes will create weird tension on the spokes, which may not be long-term.
“True” a wheel is definitely an art. Learning how to do it best is time consuming, and the worst is frustrating. If you have a bicycle repair shop in your area, that might be a perfect solution. There are bicycle studios in some places where knowledgeable people can help you repair your bike yourself (and if you enter your mind you might step in and take over). If you don't know, your local bike organization may recommend a place.
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